| 1. Round | 19/09/1981 | Hércules CF | - | Espanyol Barcelona | 2:0 | ||||
| 2. Round | 26/09/1981 | CA Osasuna | - | Hércules CF | 3:1 | ||||
| 3. Round | 04/10/1981 | Hércules CF | - | Athletic Club | 3:1 |  |
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| 4. Round | 07/10/1981 | Real Madrid | - | Hércules CF | 2:1 | ||||
| 5. Round | 10/10/1981 | Hércules CF | - | Real Betis | 3:1 | ||||
| 6. Round | 18/10/1981 | Cádiz CF | - | Hércules CF | 3:2 | ||||
| 7. Round | 25/10/1981 | Hércules CF | - | UD Las Palmas | 3:0 | ||||
| 8. Round | 31/10/1981 | Sporting Gijón | - | Hércules CF | 1:1 | ||||
| 9. Round | 07/11/1981 | Hércules CF | - | CD Castellón | 2:2 | ||||
| 10. Round | 10/11/1981 | FC Barcelona | - | Hércules CF | 5:0 | ||||
| 12. Round | 21/11/1981 | Real Sociedad | - | Hércules CF | 2:1 | ||||
| 13. Round | 28/11/1981 | Hércules CF | - | Atlético Madrid | 0:1 | |
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| 20. Round | 16/01/1982 | Athletic Club | - | Hércules CF | 3:1 | |
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| 21. Round | 23/01/1982 | Hércules CF | - | Real Madrid | 0:1 | |
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| 22. Round | 30/01/1982 | Real Betis | - | Hércules CF | 1:2 | ||||
| 25. Round | 20/02/1982 | Hércules CF | - | Sporting Gijón | 1:0 | ||||
| 26. Round | 27/02/1982 | CD Castellón | - | Hércules CF | 1:2 | ||||
| 27. Round | 06/03/1982 | Hércules CF | - | FC Barcelona | 2:2 | |
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