| 2. Round | 17/09/2022 | Real Sociedad [Women] | - | Villarreal CF [Women] | 2:0 | ||||
| 3. Round | 24/09/2022 | Real Sociedad [Women] | - | Real Betis [Women] | 2:2 | ||||
| 5. Round | 15/10/2022 | Real Sociedad [Women] | - | UDG Tenerife Sur [Women] | 1:1 | ||||
| 6. Round | 22/10/2022 | Sporting de Huelva [Women] | - | Real Sociedad [Women] | 0:2 | ||||
| 7. Round | 29/10/2022 | CD Alavés [Women] | - | Real Sociedad [Women] | 1:5 | ||||
| 8. Round | 05/11/2022 | Real Sociedad [Women] | - | Madrid CFF [Women] | 0:2 | ||||
| 9. Round | 19/11/2022 | Athletic Club [Women] | - | Real Sociedad [Women] | 1:3 | ||||
| 10. Round | 27/11/2022 | Real Sociedad [Women] | - | Levante Las Planas [Women] | 3:0 | ||||
| 11. Round | 03/12/2022 | FC Barcelona [Women] | - | Real Sociedad [Women] | 2:1 | ||||
| 12. Round | 11/12/2022 | Real Sociedad [Women] | - | Levante UD [Women] | 3:4 |
Spain