| 2. Round | 25/08/2017 | Real Sociedad | - | Villarreal CF | 3:0 | ||||
| 3. Round | 10/09/2017 | Villarreal CF | - | Real Betis | 3:1 | ||||
| 4. Round | 17/09/2017 | CD Alavés | - | Villarreal CF | 0:3 |  |
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| 5. Round | 21/09/2017 | Villarreal CF | - | Espanyol Barcelona | 0:0 |  |
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| 6. Round | 24/09/2017 | Getafe CF | - | Villarreal CF | 4:0 | |
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| 7. Round | 01/10/2017 | Villarreal CF | - | SD Eibar | 3:0 | |
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| 8. Round | 15/10/2017 | Girona FC | - | Villarreal CF | 1:2 | |
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| 9. Round | 22/10/2017 | Villarreal CF | - | UD Las Palmas | 4:0 | |
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| 10. Round | 28/10/2017 | Atlético Madrid | - | Villarreal CF | 1:1 | |
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| 11. Round | 05/11/2017 | Villarreal CF | - | Málaga CF | 2:0 | ||||
| 12. Round | 19/11/2017 | Athletic Club | - | Villarreal CF | 1:1 | ||||
| 13. Round | 26/11/2017 | Villarreal CF | - | Sevilla FC | 2:3 | |
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| 14. Round | 03/12/2017 | CD Leganés | - | Villarreal CF | 3:1 | ||||
| 15. Round | 10/12/2017 | Villarreal CF | - | FC Barcelona | 0:2 | |
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| 17. Round | 23/12/2017 | Valencia CF | - | Villarreal CF | 0:1 |
France
