| 1. Round | 24/09/1944 | Real Oviedo | - | Real Madrid | 4:0 | ||||
| 2. Round | 01/10/1944 | FC Barcelona | - | Real Oviedo | 0:1 | ||||
| 3. Round | 08/10/1944 | Real Oviedo | - | Espanyol Barcelona | 1:0 | ||||
| 4. Round | 15/10/1944 | Granada CF | - | Real Oviedo | 5:1 | ||||
| 10. Round | 26/11/1944 | Real Murcia | - | Real Oviedo | 5:1 |  |
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| 15. Round | 14/01/1945 | Real Oviedo | - | FC Barcelona | 6:0 | |
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| 16. Round | 28/01/1945 | Espanyol Barcelona | - | Real Oviedo | 3:0 | ||||
| 17. Round | 04/02/1945 | Real Oviedo | - | Granada CF | 1:1 | |
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| 19. Round | 25/02/1945 | Real Oviedo | - | CD Castellón | 2:0 | |
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| 20. Round | 18/03/1945 | Valencia CF | - | Real Oviedo | 1:1 | ||||
| 21. Round | 25/03/1945 | Real Oviedo | - | CE Sabadell | 6:2 | ||||
| 22. Round | 08/04/1945 | Athletic Club | - | Real Oviedo | 0:1 | ||||
| 23. Round | 15/04/1945 | Real Oviedo | - | Real Murcia | 3:2 | |
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| 24. Round | 22/04/1945 | Sevilla FC | - | Real Oviedo | 1:1 | |
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| 25. Round | 13/05/1945 | Sporting Gijón | - | Real Oviedo | 6:0 | ||||
| 26. Round | 20/05/1945 | Real Oviedo | - | Atlético Aviación | 3:2 | |
Spain