| 1. Round | 21/09/1966 | 1. FC Nürnberg | - | Valencia CF | 1:2 |  |
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| 1. Round | 05/10/1966 | Valencia CF | - | 1. FC Nürnberg | 2:0 | ||||
| 2. Round | 25/10/1966 | Valencia CF | - | Crvena Zvezda | 1:0 | ||||
| 2. Round | 03/11/1966 | Crvena Zvezda | - | Valencia CF | 1:2 | ||||
| Round of 16 | 16/01/1967 | Leeds United | - | Valencia CF | 1:1 | |
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| Round of 16 | 08/02/1967 | Valencia CF | - | Leeds United | 0:2 |
Spain