| 4. Round | 21/09/2024 | CDC Moscardó | - | Unión Adarve | 2:0 | ||||
| 5. Round | 29/09/2024 | Unión Adarve | - | CD Atlético Paso | 1:0 | ||||
| 12. Round | 17/11/2024 | Unión Adarve | - | Real Madrid C | 1:0 |  |
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| 13. Round | 24/11/2024 | CD Unión Sur Yaiza | - | Unión Adarve | 0:1 | ||||
| 17. Round | 21/12/2024 | CD Coria | - | Unión Adarve | 1:0 | ||||
| 18. Round | 12/01/2025 | CDA Navalcarnero | - | Unión Adarve | 3:0 | |
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| 21. Round | 02/02/2025 | Unión Adarve | - | CDC Moscardó | 1:1 | ||||
| 22. Round | 09/02/2025 | CD Atlético Paso | - | Unión Adarve | 3:2 | ||||
| 25. Round | 02/03/2025 | Unión Adarve | - | CF Talavera | 1:2 | ||||
| 26. Round | 09/03/2025 | CP Cacereño | - | Unión Adarve | 1:0 | ||||
| 27. Round | 16/03/2025 | Unión Adarve | - | UD SS Reyes | 0:1 | ||||
| 32. Round | 20/04/2025 | Unión Adarve | - | UB Conquense | 0:0 | ||||
| 33. Round | 27/04/2025 | CD Illescas | - | Unión Adarve | 2:1 | |
Spain