| 18. Round | 09/02/2025 | Espanyol Barcelona [Women] | - | FC Barcelona [Women] | 0:2 | ||||
| 19. Round | 16/02/2025 | Granada CF [Women] | - | Espanyol Barcelona [Women] | 2:1 | ||||
| 20. Round | 02/03/2025 | Espanyol Barcelona [Women] | - | Deportivo La Coruña [Women] | 1:1 | ||||
| 21. Round | 08/03/2025 | Espanyol Barcelona [Women] | - | Madrid CFF [Women] | 3:3 | ||||
| 22. Round | 16/03/2025 | Atlético Madrid [Women] | - | Espanyol Barcelona [Women] | 1:1 | ||||
| 23. Round | 22/03/2025 | Espanyol Barcelona [Women] | - | Levante UD [Women] | 1:0 |  |
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| 24. Round | 29/03/2025 | Costa Adeje Tenerife [Women] | - | Espanyol Barcelona [Women] | 4:1 | |
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| 25. Round | 13/04/2025 | Valencia CF [Women] | - | Espanyol Barcelona [Women] | 1:1 | ||||
| 27. Round | 26/04/2025 | SD Eibar [Women] | - | Espanyol Barcelona [Women] | 1:1 | ||||
| 28. Round | 03/05/2025 | Espanyol Barcelona [Women] | - | Real Sociedad [Women] | 0:3 | ||||
| 29. Round | 11/05/2025 | Athletic Club [Women] | - | Espanyol Barcelona [Women] | 1:0 | ||||
| 30. Round | 18/05/2025 | Espanyol Barcelona [Women] | - | Real Betis [Women] | 6:2 |  |
Spain