| 2. Round | 17/09/2022 | Real Sociedad [Women] | - | Villarreal CF [Women] | 2:0 | ||||
| 3. Round | 25/09/2022 | Villarreal CF [Women] | - | FC Barcelona [Women] | 1:4 | ||||
| 4. Round | 01/10/2022 | CD Alavés [Women] | - | Villarreal CF [Women] | 0:4 | ||||
| 20. Round | 05/03/2023 | FC Barcelona [Women] | - | Villarreal CF [Women] | 5:0 | ||||
| 21. Round | 12/03/2023 | Villarreal CF [Women] | - | Alhama CF [Women] | 3:1 | ||||
| 22. Round | 19/03/2023 | Villarreal CF [Women] | - | Levante Las Planas [Women] | 0:0 | ||||
| 23. Round | 25/03/2023 | Real Betis [Women] | - | Villarreal CF [Women] | 1:1 | ||||
| 24. Round | 01/04/2023 | Villarreal CF [Women] | - | UDG Tenerife Sur [Women] | 1:2 | ||||
| 25. Round | 15/04/2023 | Levante UD [Women] | - | Villarreal CF [Women] | 3:1 |  |
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| 26. Round | 23/04/2023 | Real Madrid [Women] | - | Villarreal CF [Women] | 2:1 | ||||
| 27. Round | 30/04/2023 | Villarreal CF [Women] | - | Real Sociedad [Women] | 0:1 | ||||
| 28. Round | 07/05/2023 | Sporting de Huelva [Women] | - | Villarreal CF [Women] | 1:1 | ||||
| 29. Round | 13/05/2023 | Villarreal CF [Women] | - | Atlético Madrid [Women] | 1:1 | ||||
| 30. Round | 20/05/2023 | Athletic Club [Women] | - | Villarreal CF [Women] | 1:1 |
Spain