| 1. Round | 23/09/1945 | FC Barcelona | - | Sporting Gijón | 2:0 | ||||
| 15. Round | 13/01/1946 | Hércules CF | - | Sporting Gijón | 2:1 |  |
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| 16. Round | 20/01/1946 | Sporting Gijón | - | RC Celta | 2:1 | ||||
| 17. Round | 27/01/1946 | CD Castellón | - | Sporting Gijón | 2:0 | ||||
| 18. Round | 03/02/1946 | Sporting Gijón | - | Sevilla FC | 1:2 | ||||
| 19. Round | 10/02/1946 | Real Madrid | - | Sporting Gijón | 2:2 | |
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| 20. Round | 17/02/1946 | Espanyol Barcelona | - | Sporting Gijón | 2:2 | ||||
| 21. Round | 24/02/1946 | Sporting Gijón | - | CD Alcoyano | 1:1 | ||||
| 22. Round | 03/03/1946 | Atlético Aviación | - | Sporting Gijón | 2:0 | ||||
| 25. Round | 24/03/1946 | Sporting Gijón | - | Real Murcia | 0:2 |
Spain