| 3. Round | 04/10/2006 | CD Castellón | - | Cádiz CF | 1:0 | ||||
| 4. Round | 25/10/2006 | CD Castellón | - | Villarreal CF | 0:2 |  |
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| 4. Round | 08/11/2006 | Villarreal CF | - | CD Castellón | 2:0 | |
| 3. Round | 04/10/2006 | CD Castellón | - | Cádiz CF | 1:0 | ||||
| 4. Round | 25/10/2006 | CD Castellón | - | Villarreal CF | 0:2 | |
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| 4. Round | 08/11/2006 | Villarreal CF | - | CD Castellón | 2:0 | |
| Daniel Alberto Pendín Sánchez | |
| Born: | 28.10.1974 |
| Place of birth: |
Santa Fé, 
Argentina |
| Nationality: |
Argentina
Spain |
| Height: | 186 cm |
| Weight: | 80 kg |
| Position(s): | Defensive Midfielder |
| Foot: | left |