| 16. Round | 19/12/2000 | Athletic Club | - | Valencia CF | 1:1 | ||||
| 21. Round | 02/02/2001 | FC Barcelona | - | Athletic Club | 7:0 | ||||
| 22. Round | 09/02/2001 | Athletic Club | - | Real Madrid | 1:0 | ||||
| 30. Round | 14/04/2001 | Athletic Club | - | Espanyol Barcelona | 0:1 | ||||
| 31. Round | 21/04/2001 | Rayo Vallecano | - | Athletic Club | 1:2 | ||||
| 32. Round | 28/04/2001 | Athletic Club | - | CD Alavés | 2:0 | ||||
| 33. Round | 05/05/2001 | Real Oviedo | - | Athletic Club | 5:0 | ||||
| 35. Round | 17/05/2001 | Valencia CF | - | Athletic Club | 1:0 |
Spain