| 4. Round | 18/09/2011 | Athletic Club | - | Real Betis | 2:3 |  |
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| 5. Round | 21/09/2011 | Málaga CF | - | Athletic Club | 1:0 | ||||
| 6. Round | 24/09/2011 | Athletic Club | - | Villarreal CF | 1:1 | ||||
| 11. Round | 30/10/2011 | Sporting Gijón | - | Athletic Club | 1:1 | ||||
| 14. Round | 27/11/2011 | Athletic Club | - | Granada CF | 0:1 | ||||
| 16. Round | 11/12/2011 | Athletic Club | - | Racing Santander | 1:1 | ||||
| 17. Round | 17/12/2011 | Athletic Club | - | Real Zaragoza | 2:1 | ||||
| 21. Round | 28/01/2012 | Rayo Vallecano | - | Athletic Club | 2:3 | ||||
| 22. Round | 04/02/2012 | Athletic Club | - | Espanyol Barcelona | 3:3 |  |
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| 25. Round | 26/02/2012 | Villarreal CF | - | Athletic Club | 2:2 | ||||
| 29. Round | 21/03/2012 | Atlético Madrid | - | Athletic Club | 2:1 | ||||
| 35. Round | 22/04/2012 | Racing Santander | - | Athletic Club | 0:1 | ||||
| 37. Round | 05/05/2012 | Athletic Club | - | Getafe CF | 0:0 |
Spain