| 2. Round | 30/09/1945 | Sporting Gijón | - | Hércules CF | 2:0 |  |
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| 3. Round | 07/10/1945 | RC Celta | - | Sporting Gijón | 2:3 | ||||
| 4. Round | 14/10/1945 | Sporting Gijón | - | CD Castellón | 2:0 | |
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| 5. Round | 21/10/1945 | Sevilla FC | - | Sporting Gijón | 3:2 | ||||
| 6. Round | 28/10/1945 | Sporting Gijón | - | Real Madrid | 1:1 | ||||
| 7. Round | 04/11/1945 | Sporting Gijón | - | Espanyol Barcelona | 4:1 | ||||
| 8. Round | 18/11/1945 | CD Alcoyano | - | Sporting Gijón | 4:1 | ||||
| 9. Round | 25/11/1945 | Sporting Gijón | - | Atlético Aviación | 3:2 | |
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| 10. Round | 02/12/1945 | Athletic Club | - | Sporting Gijón | 2:3 | |
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| 11. Round | 09/12/1945 | Sporting Gijón | - | Valencia CF | 1:2 | ||||
| 13. Round | 30/12/1945 | Sporting Gijón | - | Real Oviedo | 1:0 | ||||
| 14. Round | 06/01/1946 | Sporting Gijón | - | FC Barcelona | 2:0 | ||||
| 19. Round | 10/02/1946 | Real Madrid | - | Sporting Gijón | 2:2 | ||||
| 26. Round | 31/03/1946 | Real Oviedo | - | Sporting Gijón | 2:2 | |
Spain