| 13. Round | 01/12/1990 | Sporting Gijón | - | Cádiz CF | 3:1 |  |
|||
| 14. Round | 08/12/1990 | Real Sociedad | - | Sporting Gijón | 1:0 | |
|||
| 15. Round | 15/12/1990 | Sporting Gijón | - | CD Logroñés | 1:0 | ||||
| 16. Round | 29/12/1990 | Real Oviedo | - | Sporting Gijón | 0:0 | |
|||
| 17. Round | 05/01/1991 | Sporting Gijón | - | Real Madrid | 0:2 | |
|||
| 18. Round | 12/01/1991 | Espanyol Barcelona | - | Sporting Gijón | 0:2 | ||||
| 27. Round | 23/03/1991 | Sporting Gijón | - | FC Barcelona | 1:0 | ||||
| 34. Round | 10/05/1991 | CD Logroñés | - | Sporting Gijón | 1:2 | ||||
| 36. Round | 24/05/1991 | Real Madrid | - | Sporting Gijón | 2:1 | ||||
| 37. Round | 01/06/1991 | Sporting Gijón | - | Espanyol Barcelona | 3:0 | ||||
| 38. Round | 08/06/1991 | Valencia CF | - | Sporting Gijón | 0:1 |
Spain