| 6. Round | 28/10/1945 | Athletic Club | - | Hércules CF | 6:0 | ||||
| 9. Round | 25/11/1945 | Hércules CF | - | Real Oviedo | 0:3 | ||||
| 10. Round | 02/12/1945 | FC Barcelona | - | Hércules CF | 5:3 | ||||
| 13. Round | 30/12/1945 | CD Castellón | - | Hércules CF | 2:1 | ||||
| 25. Round | 24/03/1946 | RC Celta | - | Hércules CF | 4:2 | ||||
| 26. Round | 31/03/1946 | Hércules CF | - | CD Castellón | 1:2 |
Spain