| 2. Round | 05/09/1964 | RC Strasbourg | - | US Valenciennes-Anzin | 3:3 | ||||
| 3. Round | 13/09/1964 | US Valenciennes-Anzin | - | Nîmes Olympique | 1:0 | ||||
| 4. Round | 19/09/1964 | Toulouse FC | - | US Valenciennes-Anzin | 1:0 | ||||
| 5. Round | 27/09/1964 | US Valenciennes-Anzin | - | Angers SCO | 0:0 | ||||
| 8. Round | 17/10/1964 | Olympique Lyonnais | - | US Valenciennes-Anzin | 1:0 | ||||
| 11. Round | 08/11/1964 | Sporting Club de Toulon | - | US Valenciennes-Anzin | 1:3 | ||||
| 12. Round | 15/11/1964 | US Valenciennes-Anzin | - | FC Nantes | 2:1 |
France