| 1. Round | 02/09/1972 | Sporting Gijón | - | Real Betis | 1:0 | ||||
| 2. Round | 09/09/1972 | Real Madrid | - | Sporting Gijón | 1:0 | ||||
| 3. Round | 16/09/1972 | Sporting Gijón | - | Espanyol Barcelona | 0:0 | ||||
| 4. Round | 23/09/1972 | Athletic Club | - | Sporting Gijón | 2:0 | ||||
| 5. Round | 01/10/1972 | Sporting Gijón | - | Real Sociedad | 3:0 | ||||
| 6. Round | 07/10/1972 | CD Málaga | - | Sporting Gijón | 1:0 | ||||
| 8. Round | 29/10/1972 | CD Castellón | - | Sporting Gijón | 1:0 | ||||
| 9. Round | 04/11/1972 | Burgos CF | - | Sporting Gijón | 2:1 | ||||
| 10. Round | 11/11/1972 | Sporting Gijón | - | UD Las Palmas | 2:2 | ||||
| 11. Round | 18/11/1972 | Atlético Madrid | - | Sporting Gijón | 0:1 | ||||
| 12. Round | 25/11/1972 | Sporting Gijón | - | FC Barcelona | 1:1 | ||||
| 13. Round | 02/12/1972 | Granada CF | - | Sporting Gijón | 1:0 | ||||
| 14. Round | 09/12/1972 | Sporting Gijón | - | Real Zaragoza | 3:0 | ||||
| 15. Round | 16/12/1972 | Deportivo La Coruña | - | Sporting Gijón | 2:1 | ||||
| 16. Round | 30/12/1972 | Sporting Gijón | - | Valencia CF | 1:1 | ||||
| 17. Round | 06/01/1973 | Real Oviedo | - | Sporting Gijón | 1:0 | ||||
| 24. Round | 10/03/1973 | RC Celta | - | Sporting Gijón | 3:0 |
Spain