| 1. Round | 28/08/2010 | Hércules CF | - | Athletic Club | 0:1 | ||||
| 2. Round | 11/09/2010 | Athletic Club | - | Atlético Madrid | 1:2 |  |
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| 3. Round | 18/09/2010 | Sporting Gijón | - | Athletic Club | 2:2 | |
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| 4. Round | 21/09/2010 | Athletic Club | - | RCD Mallorca | 3:0 | ||||
| 5. Round | 25/09/2010 | Athletic Club | - | FC Barcelona | 1:3 |  |
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| 12. Round | 20/11/2010 | Real Madrid | - | Athletic Club | 5:1 | |
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| 13. Round | 28/11/2010 | Athletic Club | - | CA Osasuna | 1:0 | |
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| 14. Round | 05/12/2010 | Real Sociedad | - | Athletic Club | 2:0 | ||||
| 15. Round | 12/12/2010 | Athletic Club | - | Espanyol Barcelona | 2:1 | |
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| 24. Round | 20/02/2011 | FC Barcelona | - | Athletic Club | 2:1 | ||||
| 30. Round | 04/04/2011 | UD Almería | - | Athletic Club | 1:3 | ||||
| 32. Round | 17/04/2011 | CA Osasuna | - | Athletic Club | 1:2 | ||||
| 33. Round | 23/04/2011 | Athletic Club | - | Real Sociedad | 2:1 | |
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| 34. Round | 02/05/2011 | Espanyol Barcelona | - | Athletic Club | 2:1 | ||||
| 36. Round | 10/05/2011 | Deportivo La Coruña | - | Athletic Club | 2:1 | |
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| 37. Round | 15/05/2011 | Athletic Club | - | Málaga CF | 1:1 | ||||
| 38. Round | 21/05/2011 | Racing Santander | - | Athletic Club | 1:2 |
Venezuela
Spain 
