| 4. Round | 16/09/2012 | Espanyol Barcelona | - | Athletic Club | 3:3 |  |
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| 6. Round | 29/09/2012 | Real Sociedad | - | Athletic Club | 2:0 |  |
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| 8. Round | 20/10/2012 | Valencia CF | - | Athletic Club | 3:2 | ||||
| 9. Round | 28/10/2012 | Athletic Club | - | Getafe CF | 1:2 | ||||
| 10. Round | 04/11/2012 | Granada CF | - | Athletic Club | 1:2 | |
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| 11. Round | 11/11/2012 | Athletic Club | - | Sevilla FC | 2:1 | ||||
| 13. Round | 25/11/2012 | Athletic Club | - | Deportivo La Coruña | 1:1 | |
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| 14. Round | 01/12/2012 | FC Barcelona | - | Athletic Club | 5:1 | ||||
| 15. Round | 09/12/2012 | Athletic Club | - | RC Celta | 1:0 | |
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| 18. Round | 05/01/2013 | Levante UD | - | Athletic Club | 3:1 | ||||
| 19. Round | 11/01/2013 | Athletic Club | - | Rayo Vallecano | 1:2 |
Venezuela
Spain 
