| 2. Round | 21/09/1963 | FC Barcelona | - | Pontevedra CF | 3:1 | ||||
| 4. Round | 06/10/1963 | FC Barcelona | - | Atlético Madrid | 3:1 | ||||
| 5. Round | 13/10/1963 | Real Zaragoza | - | FC Barcelona | 2:0 | ||||
| 6. Round | 20/10/1963 | FC Barcelona | - | Real Valladolid | 2:1 | ||||
| 7. Round | 03/11/1963 | FC Barcelona | - | Sevilla FC | 6:0 | ||||
| 10. Round | 24/11/1963 | Athletic Club | - | FC Barcelona | 2:0 | ||||
| 12. Round | 15/12/1963 | Real Madrid | - | FC Barcelona | 4:0 | ||||
| 13. Round | 22/12/1963 | FC Barcelona | - | Córdoba CF | 3:1 | ||||
| 14. Round | 29/12/1963 | Espanyol Barcelona | - | FC Barcelona | 2:2 | ||||
| 27. Round | 30/03/1964 | FC Barcelona | - | Real Madrid | 1:2 |
Spain