| 1. Round | 13/09/1964 | UD Las Palmas | - | FC Barcelona | 2:1 | ||||
| 2. Round | 20/09/1964 | FC Barcelona | - | Atlético Madrid | 2:3 | ||||
| 5. Round | 11/10/1964 | Levante UD | - | FC Barcelona | 5:1 | ||||
| 6. Round | 18/10/1964 | FC Barcelona | - | Athletic Club | 4:0 | ||||
| 7. Round | 25/10/1964 | Sevilla FC | - | FC Barcelona | 2:1 | ||||
| 8. Round | 01/11/1964 | FC Barcelona | - | Espanyol Barcelona | 1:0 | ||||
| 16. Round | 03/01/1965 | FC Barcelona | - | UD Las Palmas | 4:0 | ||||
| 22. Round | 14/02/1965 | FC Barcelona | - | Sevilla FC | 4:3 | ||||
| 23. Round | 21/02/1965 | Espanyol Barcelona | - | FC Barcelona | 0:0 | ||||
| 26. Round | 21/03/1965 | FC Barcelona | - | Elche CF | 1:1 | ||||
| 27. Round | 28/03/1965 | Real Oviedo | - | FC Barcelona | 2:0 | ||||
| 28. Round | 04/04/1965 | FC Barcelona | - | Valencia CF | 2:0 | ||||
| 29. Round | 11/04/1965 | Real Zaragoza | - | FC Barcelona | 2:0 | ||||
| 30. Round | 18/04/1965 | FC Barcelona | - | Real Betis | 0:0 |
Spain