| 4. Round | 26/09/1965 | Pontevedra CF | - | FC Barcelona | 2:0 | ||||
| 5. Round | 03/10/1965 | FC Barcelona | - | Valencia CF | 1:2 | ||||
| 8. Round | 31/10/1965 | Espanyol Barcelona | - | FC Barcelona | 1:1 | ||||
| 9. Round | 14/11/1965 | FC Barcelona | - | Real Zaragoza | 0:1 | ||||
| 30. Round | 03/04/1966 | UD Las Palmas | - | FC Barcelona | 2:1 |
Spain