1. Round | 13/08/2022 | Real Valladolid | - | Villarreal CF | 0:3 | ||||
2. Round | 21/08/2022 | Atlético Madrid | - | Villarreal CF | 0:2 | ||||
3. Round | 28/08/2022 | Getafe CF | - | Villarreal CF | 0:0 | ||||
4. Round | 04/09/2022 | Villarreal CF | - | Elche CF | 4:0 | ||||
5. Round | 11/09/2022 | Real Betis | - | Villarreal CF | 1:0 | ||||
6. Round | 18/09/2022 | Villarreal CF | - | Sevilla FC | 1:1 | ||||
7. Round | 01/10/2022 | Cádiz CF | - | Villarreal CF | 0:0 | ||||
8. Round | 09/10/2022 | Real Sociedad | - | Villarreal CF | 1:0 | ||||
11. Round | 23/10/2022 | Villarreal CF | - | UD Almería | 2:1 | ||||
12. Round | 30/10/2022 | Athletic Bilbao | - | Villarreal CF | 1:0 | ||||
14. Round | 09/11/2022 | Espanyol Barcelona | - | Villarreal CF | 0:1 | ||||
16. Round | 07/01/2023 | Villarreal CF | - | Real Madrid | 2:1 | ||||
17. Round | 13/01/2023 | RC Celta | - | Villarreal CF | 1:1 | ||||
19. Round | 30/01/2023 | Villarreal CF | - | Rayo Vallecano | 0:1 | ||||
20. Round | 04/02/2023 | Elche CF | - | Villarreal CF | 3:1 | ||||
21. Round | 12/02/2023 | Villarreal CF | - | FC Barcelona | 0:1 |