| 1. Round | 22/08/1965 | Red Star FC | - | US Valenciennes-Anzin | 2:0 | ||||
| 17. Round | 28/11/1965 | AS Saint-Étienne | - | US Valenciennes-Anzin | 5:1 | ||||
| 27. Round | 28/04/1966 | Olympique Lyonnais | - | US Valenciennes-Anzin | 0:1 | ||||
| 34. Round | 07/05/1966 | US Valenciennes-Anzin | - | FC Rouen 1899 | 1:1 | ||||
| 35. Round | 15/05/1966 | OGC Nice | - | US Valenciennes-Anzin | 1:1 | ||||
| 36. Round | 18/05/1966 | US Valenciennes-Anzin | - | AS Saint-Étienne | 3:1 |
France