| 2. Round | 17/09/2022 | Real Sociedad [Women] | - | Villarreal CF [Women] | 2:0 | ||||
| 3. Round | 24/09/2022 | Real Sociedad [Women] | - | Real Betis [Women] | 2:2 |  |
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| 4. Round | 02/10/2022 | Sevilla FC [Women] | - | Real Sociedad [Women] | 2:2 |  |
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| 5. Round | 15/10/2022 | Real Sociedad [Women] | - | UDG Tenerife Sur [Women] | 1:1 | |
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| 6. Round | 22/10/2022 | Sporting de Huelva [Women] | - | Real Sociedad [Women] | 0:2 | ||||
| 7. Round | 29/10/2022 | CD Alavés [Women] | - | Real Sociedad [Women] | 1:5 | |
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| 1. Round | 01/11/2022 | Atlético Madrid [Women] | - | Real Sociedad [Women] | 1:1 | ||||
| 8. Round | 05/11/2022 | Real Sociedad [Women] | - | Madrid CFF [Women] | 0:2 | ||||
| 9. Round | 19/11/2022 | Athletic Club [Women] | - | Real Sociedad [Women] | 1:3 | |
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| 10. Round | 27/11/2022 | Real Sociedad [Women] | - | Levante Las Planas [Women] | 3:0 | |
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| 11. Round | 03/12/2022 | FC Barcelona [Women] | - | Real Sociedad [Women] | 2:1 | ||||
| 12. Round | 11/12/2022 | Real Sociedad [Women] | - | Levante UD [Women] | 3:4 | |
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| 14. Round | 07/01/2023 | Real Sociedad [Women] | - | Alhama CF [Women] | 2:1 | ||||
| 15. Round | 15/01/2023 | Valencia CF [Women] | - | Real Sociedad [Women] | 2:1 | |
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