| 1. Round | 27/08/2006 | Athletic Club | - | Real Sociedad | 1:1 | ||||
| 3. Round | 17/09/2006 | Athletic Club | - | Atlético Madrid | 1:4 | ||||
| 4. Round | 24/09/2006 | Getafe CF | - | Athletic Club | 0:0 | ||||
| 5. Round | 30/09/2006 | Athletic Club | - | FC Barcelona | 1:3 | ||||
| 6. Round | 15/10/2006 | Gimnàstic de Tarragona | - | Athletic Club | 2:3 | ||||
| 12. Round | 26/11/2006 | Athletic Club | - | Sevilla FC | 1:3 | ||||
| 14. Round | 10/12/2006 | Athletic Club | - | Recreativo Huelva | 4:2 |  |
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| 15. Round | 16/12/2006 | Deportivo La Coruña | - | Athletic Club | 0:2 | ||||
| 16. Round | 19/12/2006 | Athletic Club | - | Real Zaragoza | 0:0 | ||||
| 17. Round | 07/01/2007 | RCD Mallorca | - | Athletic Club | 1:3 | ||||
| 19. Round | 21/01/2007 | Levante UD | - | Athletic Club | 0:0 | ||||
| 20. Round | 28/01/2007 | Real Sociedad | - | Athletic Club | 0:2 | ||||
| 27. Round | 17/03/2007 | Athletic Club | - | CA Osasuna | 0:3 | ||||
| 28. Round | 01/04/2007 | Racing Santander | - | Athletic Club | 5:4 | ||||
| 29. Round | 07/04/2007 | Athletic Club | - | Valencia CF | 1:0 | ||||
| 30. Round | 15/04/2007 | Athletic Club | - | Espanyol Barcelona | 2:1 |
Spain