| 1. Round | 13/08/2023 | Getafe CF | - | FC Barcelona | 0:0 |  |
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| 2. Round | 20/08/2023 | FC Barcelona | - | Cádiz CF | 2:0 | |
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| 3. Round | 27/08/2023 | Villarreal CF | - | FC Barcelona | 3:4 |  |
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| 4. Round | 03/09/2023 | CA Osasuna | - | FC Barcelona | 1:2 | ||||
| 5. Round | 16/09/2023 | FC Barcelona | - | Real Betis | 5:0 | ||||
| 6. Round | 23/09/2023 | FC Barcelona | - | RC Celta | 3:2 | |
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| 7. Round | 26/09/2023 | RCD Mallorca | - | FC Barcelona | 2:2 | ||||
| 8. Round | 29/09/2023 | FC Barcelona | - | Sevilla FC | 1:0 | ||||
| 9. Round | 08/10/2023 | Granada CF | - | FC Barcelona | 2:2 | ||||
| 10. Round | 22/10/2023 | FC Barcelona | - | Athletic Club | 1:0 | |
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| 11. Round | 28/10/2023 | FC Barcelona | - | Real Madrid | 1:2 | ||||
| 12. Round | 04/11/2023 | Real Sociedad | - | FC Barcelona | 0:1 | |
Spain
