| 6. Round | 10/10/1965 | Real Betis | - | UD Las Palmas | 1:0 | ||||
| 7. Round | 17/10/1965 | UD Las Palmas | - | Sevilla FC | 1:0 | ||||
| 8. Round | 31/10/1965 | UD Las Palmas | - | Pontevedra CF | 0:1 | ||||
| 10. Round | 21/11/1965 | UD Las Palmas | - | Valencia CF | 0:2 | ||||
| 11. Round | 28/11/1965 | UD Las Palmas | - | Athletic Club | 1:1 |
Spain