| 1. Round | 19/08/1966 | Toulouse FC | - | AS Saint-Étienne | 0:2 | ||||
| 2. Round | 27/08/1966 | AS Saint-Étienne | - | Olympique Marseille | 2:0 | ||||
| 3. Round | 31/08/1966 | OGC Nice | - | AS Saint-Étienne | 1:2 | ||||
| 4. Round | 03/09/1966 | AS Saint-Étienne | - | Girondins Bordeaux | 1:1 | ||||
| 5. Round | 10/09/1966 | RC Strasbourg | - | AS Saint-Étienne | 2:1 | ||||
| 6. Round | 14/09/1966 | AS Saint-Étienne | - | FC Rouen 1899 | 3:0 | ||||
| 7. Round | 18/09/1966 | Stade Rennais | - | AS Saint-Étienne | 1:1 | ||||
| 8. Round | 23/09/1966 | AS Saint-Étienne | - | CS Sedan | 1:0 | ||||
| 9. Round | 02/10/1966 | Olympique Lyonnais | - | AS Saint-Étienne | 3:0 | ||||
| 10. Round | 09/10/1966 | AS Saint-Étienne | - | FC Nantes | 3:3 | ||||
| 11. Round | 12/10/1966 | RC Lens | - | AS Saint-Étienne | 2:0 | ||||
| 12. Round | 15/10/1966 | AS Saint-Étienne | - | US Valenciennes-Anzin | 3:1 | ||||
| 13. Round | 30/10/1966 | Stade de Paris FC | - | AS Saint-Étienne | 1:1 | ||||
| 14. Round | 01/11/1966 | AS Saint-Étienne | - | FC Sochaux | 1:0 | ||||
| 16. Round | 13/11/1966 | AS Saint-Étienne | - | Nîmes Olympique | 3:1 | ||||
| 17. Round | 20/11/1966 | AS Saint-Étienne | - | Lille OSC | 4:1 | ||||
| 15. Round | 29/11/1966 | AS Monaco | - | AS Saint-Étienne | 1:0 |
France