| 1. Round | 24/09/1944 | Atlético Aviación | - | FC Barcelona | 1:1 | ||||
| 2. Round | 01/10/1944 | FC Barcelona | - | Real Oviedo | 0:1 | ||||
| 8. Round | 12/11/1944 | Real Madrid | - | FC Barcelona | 1:0 | ||||
| 12. Round | 10/12/1944 | Athletic Club | - | FC Barcelona | 4:1 | ||||
| 15. Round | 14/01/1945 | Real Oviedo | - | FC Barcelona | 6:0 | ||||
| 16. Round | 28/01/1945 | Granada CF | - | FC Barcelona | 1:2 | ||||
| 17. Round | 04/02/1945 | FC Barcelona | - | CD Castellón | 3:1 |  |
|||
| 19. Round | 25/02/1945 | FC Barcelona | - | Real Murcia | 1:0 | ||||
| 20. Round | 18/03/1945 | Sporting Gijón | - | FC Barcelona | 2:5 | ||||
| 21. Round | 25/03/1945 | FC Barcelona | - | Real Madrid | 5:0 | |
|||
| 22. Round | 08/04/1945 | Espanyol Barcelona | - | FC Barcelona | 1:1 | |
|||
| 23. Round | 15/04/1945 | FC Barcelona | - | Deportivo La Coruña | 3:0 | |
|||
| 24. Round | 22/04/1945 | Valencia CF | - | FC Barcelona | 2:3 | ||||
| 25. Round | 13/05/1945 | FC Barcelona | - | Athletic Club | 5:2 | |
Spain