| 1. Round | 29/09/1940 | Sevilla FC | - | FC Barcelona | 11:1 | ||||
| 2. Round | 06/10/1940 | FC Barcelona | - | Valencia CF | 4:3 | ||||
| 4. Round | 20/10/1940 | FC Barcelona | - | Hércules CF | 3:2 |  |
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| 5. Round | 27/10/1940 | Atlético Aviación | - | FC Barcelona | 4:4 | ||||
| 6. Round | 03/11/1940 | FC Barcelona | - | Espanyol Barcelona | 2:3 | |
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| 7. Round | 10/11/1940 | Real Oviedo | - | FC Barcelona | 3:1 | ||||
| 8. Round | 17/11/1940 | FC Barcelona | - | RC Celta | 2:0 | ||||
| 9. Round | 24/11/1940 | Real Murcia | - | FC Barcelona | 1:3 | ||||
| 10. Round | 01/12/1940 | FC Barcelona | - | Real Madrid | 3:0 | ||||
| 11. Round | 08/12/1940 | Athletic Club | - | FC Barcelona | 3:1 | ||||
| 12. Round | 15/12/1940 | FC Barcelona | - | Sevilla FC | 4:0 | ||||
| 13. Round | 22/12/1940 | Valencia CF | - | FC Barcelona | 3:1 | |
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| 14. Round | 29/12/1940 | FC Barcelona | - | Real Zaragoza | 2:0 | ||||
| 17. Round | 26/01/1941 | Espanyol Barcelona | - | FC Barcelona | 3:1 | ||||
| 18. Round | 02/02/1941 | FC Barcelona | - | Real Oviedo | 7:0 | |
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| 19. Round | 09/02/1941 | RC Celta | - | FC Barcelona | 1:4 | |
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| 20. Round | 16/02/1941 | FC Barcelona | - | Real Murcia | 3:0 | |
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| 21. Round | 23/02/1941 | Real Madrid | - | FC Barcelona | 1:2 | ||||
| 22. Round | 02/03/1941 | FC Barcelona | - | Athletic Club | 1:0 |
Spain