| 2. Round | 05/10/1941 | Espanyol Barcelona | - | FC Barcelona | 5:2 | ||||
| 4. Round | 19/10/1941 | Real Madrid | - | FC Barcelona | 4:3 |  |
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| 5. Round | 26/10/1941 | FC Barcelona | - | Valencia CF | 2:4 | |
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| 6. Round | 02/11/1941 | Real Sociedad | - | FC Barcelona | 2:0 | ||||
| 7. Round | 09/11/1941 | FC Barcelona | - | Granada CF | 4:0 | ||||
| 8. Round | 16/11/1941 | Athletic Club | - | FC Barcelona | 6:3 | ||||
| 11. Round | 07/12/1941 | Sevilla FC | - | FC Barcelona | 1:2 | ||||
| 12. Round | 14/12/1941 | FC Barcelona | - | Real Oviedo | 6:3 | |
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| 13. Round | 21/12/1941 | CD Castellón | - | FC Barcelona | 1:1 | ||||
| 14. Round | 04/01/1942 | Hércules CF | - | FC Barcelona | 3:1 | ||||
| 15. Round | 11/01/1942 | FC Barcelona | - | Espanyol Barcelona | 1:2 | ||||
| 16. Round | 18/01/1942 | RC Celta | - | FC Barcelona | 1:0 | ||||
| 17. Round | 25/01/1942 | FC Barcelona | - | Real Madrid | 0:2 | ||||
| 18. Round | 01/02/1942 | Valencia CF | - | FC Barcelona | 4:2 | |
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| 19. Round | 08/02/1942 | FC Barcelona | - | Real Sociedad | 4:2 | |
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| 20. Round | 15/02/1942 | Granada CF | - | FC Barcelona | 6:0 | ||||
| 21. Round | 22/02/1942 | FC Barcelona | - | Athletic Club | 1:2 | ||||
| 24. Round | 22/03/1942 | FC Barcelona | - | Sevilla FC | 6:2 | ||||
| 26. Round | 05/04/1942 | FC Barcelona | - | CD Castellón | 3:1 | |
Spain