| 2. Round | 28/08/2011 | Athletic Club | - | Rayo Vallecano | 1:1 | ||||
| 3. Round | 11/09/2011 | Espanyol Barcelona | - | Athletic Club | 2:1 | ||||
| 4. Round | 18/09/2011 | Athletic Club | - | Real Betis | 2:3 |  |
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| 5. Round | 21/09/2011 | Málaga CF | - | Athletic Club | 1:0 | ||||
| 6. Round | 24/09/2011 | Athletic Club | - | Villarreal CF | 1:1 | ||||
| 7. Round | 02/10/2011 | Real Sociedad | - | Athletic Club | 1:2 | |
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| 9. Round | 23/10/2011 | Valencia CF | - | Athletic Club | 1:1 |
Spain
