| 5. Round | 15/09/2024 | Girona FC | - | FC Barcelona | 1:4 | ||||
| 6. Round | 22/09/2024 | Villarreal CF | - | FC Barcelona | 1:5 | ||||
| 7. Round | 25/09/2024 | FC Barcelona | - | Getafe CF | 1:0 | ||||
| 8. Round | 28/09/2024 | CA Osasuna | - | FC Barcelona | 4:2 | ||||
| 9. Round | 06/10/2024 | CD Alavés | - | FC Barcelona | 0:3 | ||||
| 12. Round | 03/11/2024 | FC Barcelona | - | Espanyol Barcelona | 3:1 | ||||
| 14. Round | 23/11/2024 | RC Celta | - | FC Barcelona | 2:2 |  |
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| 15. Round | 30/11/2024 | FC Barcelona | - | UD Las Palmas | 1:2 | ||||
| 16. Round | 07/12/2024 | Real Betis | - | FC Barcelona | 2:2 | |
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| 21. Round | 26/01/2025 | FC Barcelona | - | Valencia CF | 7:1 | ||||
| 24. Round | 17/02/2025 | FC Barcelona | - | Rayo Vallecano | 1:0 | ||||
| 26. Round | 02/03/2025 | FC Barcelona | - | Real Sociedad | 4:0 | ||||
| 33. Round | 22/04/2025 | FC Barcelona | - | RCD Mallorca | 1:0 | ||||
| 34. Round | 03/05/2025 | Real Valladolid | - | FC Barcelona | 1:2 | ||||
| 35. Round | 11/05/2025 | FC Barcelona | - | Real Madrid | 4:3 | ||||
| 36. Round | 15/05/2025 | Espanyol Barcelona | - | FC Barcelona | 0:2 | ||||
| 37. Round | 18/05/2025 | FC Barcelona | - | Villarreal CF | 2:3 |
Spain