| 1. Round | 10/11/1999 | CF Extremadura | - | CD Alavés | 1:1 |  |
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| 2. Round | 15/12/1999 | Real Unión | - | CD Alavés | 1:0 | |
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| 2. Round | 12/01/2000 | CD Alavés | - | Real Unión | 2:1 |
| 1. Round | 10/11/1999 | CF Extremadura | - | CD Alavés | 1:1 | |
|
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| 2. Round | 15/12/1999 | Real Unión | - | CD Alavés | 1:0 | |
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| 2. Round | 12/01/2000 | CD Alavés | - | Real Unión | 2:1 |
| Hermes Aldo Desio | |
| Born: | 20.01.1970 |
| Place of birth: |
Rosario, 
Argentina |
| Nationality: |
Argentina
Spain |
| Height: | 176 cm |
| Weight: | 73 kg |
| Position(s): | Central Midfielder |