| 2. Round | 30/09/1945 | Sporting Gijón | - | Hércules CF | 2:0 | ||||
| 10. Round | 02/12/1945 | FC Barcelona | - | Hércules CF | 5:3 | ||||
| 15. Round | 13/01/1946 | Hércules CF | - | Sporting Gijón | 2:1 | ||||
| 16. Round | 20/01/1946 | Espanyol Barcelona | - | Hércules CF | 5:2 |  |
|||
| 18. Round | 03/02/1946 | Atlético Aviación | - | Hércules CF | 5:2 | |
|||
| 19. Round | 10/02/1946 | Hércules CF | - | Athletic Club | 0:0 | ||||
| 20. Round | 17/02/1946 | Valencia CF | - | Hércules CF | 2:2 | ||||
| 21. Round | 24/02/1946 | Hércules CF | - | Real Murcia | 2:0 | ||||
| 22. Round | 03/03/1946 | Real Oviedo | - | Hércules CF | 2:0 | ||||
| 23. Round | 10/03/1946 | Hércules CF | - | FC Barcelona | 0:0 | ||||
| 24. Round | 17/03/1946 | Hércules CF | - | Real Madrid | 2:3 | ||||
| 25. Round | 24/03/1946 | RC Celta | - | Hércules CF | 4:2 | ||||
| 26. Round | 31/03/1946 | Hércules CF | - | CD Castellón | 1:2 |
Spain