| Group 5 | 08/02/2006 | LDU Quito | - | Vélez Sarsfield | 1:3 | ||||
| Group 5 | 15/02/2006 | Vélez Sarsfield | - | Rocha | 3:0 | ||||
| Group 5 | 08/03/2006 | Universitario de Deportes | - | Vélez Sarsfield | 0:1 | ||||
| Group 5 | 14/03/2006 | Vélez Sarsfield | - | Universitario de Deportes | 4:3 | ||||
| Group 5 | 11/04/2006 | Rocha | - | Vélez Sarsfield | 0:5 | ||||
| Round of 16 | 28/04/2006 | Newell's Old Boys | - | Vélez Sarsfield | 2:4 | ||||
| Round of 16 | 03/05/2006 | Vélez Sarsfield | - | Newell's Old Boys | 2:2 | ||||
| Quarter-finals | 10/05/2006 | Deportivo Guadalajara | - | Vélez Sarsfield | 0:0 | ||||
| Quarter-finals | 21/07/2006 | Vélez Sarsfield | - | Deportivo Guadalajara | 1:2 |  |
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