| Round of 16 | 16/01/2022 | Atlético Baleares | - | Valencia CF | 0:1 |
| Round of 16 | 16/01/2022 | Atlético Baleares | - | Valencia CF | 0:1 |
| Hugo Rodríguez Romero | |
| Born: | 30.12.1989 |
| Place of birth: |
Jerez de la Frontera, 
Spain |
| Nationality: |
Spain
|
| Height: | 181 cm |
| Weight: | 76 kg |
| Position(s): | Left Midfielder Right Midfielder |
| Foot: | right |