| 2. Round | 23/08/2013 | Athletic Club | - | CA Osasuna | 2:0 | ||||
| 3. Round | 01/09/2013 | Real Madrid | - | Athletic Club | 3:1 | ||||
| 4. Round | 16/09/2013 | Athletic Club | - | RC Celta | 3:2 |  |
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| 10. Round | 28/10/2013 | Getafe CF | - | Athletic Club | 0:1 | ||||
| 11. Round | 31/10/2013 | Athletic Club | - | Elche CF | 2:2 | ||||
| 38. Round | 18/05/2014 | UD Almería | - | Athletic Club | 0:0 |
Spain