| 6. Round | 22/09/2024 | Villarreal CF | - | FC Barcelona | 1:5 | ||||
| 7. Round | 25/09/2024 | FC Barcelona | - | Getafe CF | 1:0 | ||||
| 8. Round | 28/09/2024 | CA Osasuna | - | FC Barcelona | 4:2 | ||||
| 9. Round | 06/10/2024 | CD Alavés | - | FC Barcelona | 0:3 | ||||
| 10. Round | 20/10/2024 | FC Barcelona | - | Sevilla FC | 5:1 | ||||
| 11. Round | 26/10/2024 | Real Madrid | - | FC Barcelona | 0:4 |  |
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| 12. Round | 03/11/2024 | FC Barcelona | - | Espanyol Barcelona | 3:1 | ||||
| 13. Round | 10/11/2024 | Real Sociedad | - | FC Barcelona | 1:0 | ||||
| 14. Round | 23/11/2024 | RC Celta | - | FC Barcelona | 2:2 | ||||
| 15. Round | 30/11/2024 | FC Barcelona | - | UD Las Palmas | 1:2 | ||||
| 19. Round | 03/12/2024 | RCD Mallorca | - | FC Barcelona | 1:5 | ||||
| 16. Round | 07/12/2024 | Real Betis | - | FC Barcelona | 2:2 | ||||
| 17. Round | 15/12/2024 | FC Barcelona | - | CD Leganés | 0:1 | ||||
| 18. Round | 21/12/2024 | FC Barcelona | - | Atlético Madrid | 1:2 | ||||
| 20. Round | 18/01/2025 | Getafe CF | - | FC Barcelona | 1:1 | ||||
| 38. Round | 25/05/2025 | Athletic Club | - | FC Barcelona | 0:3 |
Spain