| 1. Round | 19/08/2012 | Athletic Club | - | Real Betis | 3:5 | ||||
| 2. Round | 27/08/2012 | Atlético Madrid | - | Athletic Club | 4:0 |  |
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| 3. Round | 02/09/2012 | Athletic Club | - | Real Valladolid | 2:0 | ||||
| 4. Round | 16/09/2012 | Espanyol Barcelona | - | Athletic Club | 3:3 | |
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| 8. Round | 20/10/2012 | Valencia CF | - | Athletic Club | 3:2 |
Spain