| 1. Round | 19/08/2012 | Athletic Club | - | Real Betis | 3:5 | ||||
| 2. Round | 27/08/2012 | Atlético Madrid | - | Athletic Club | 4:0 | ||||
| 3. Round | 02/09/2012 | Athletic Club | - | Real Valladolid | 2:0 | ||||
| 4. Round | 16/09/2012 | Espanyol Barcelona | - | Athletic Club | 3:3 | ||||
| 5. Round | 23/09/2012 | Athletic Club | - | Málaga CF | 0:0 | ||||
| 6. Round | 29/09/2012 | Real Sociedad | - | Athletic Club | 2:0 | ||||
| 9. Round | 28/10/2012 | Athletic Club | - | Getafe CF | 1:2 | ||||
| 11. Round | 11/11/2012 | Athletic Club | - | Sevilla FC | 2:1 |
Spain