| 4. Round | 23/09/2009 | CD Tenerife | - | Athletic Club | 1:0 |  |
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| 13. Round | 06/12/2009 | Athletic Club | - | Valencia CF | 1:2 | ||||
| 19. Round | 23/01/2010 | Deportivo La Coruña | - | Athletic Club | 3:1 | ||||
| 20. Round | 30/01/2010 | Espanyol Barcelona | - | Athletic Club | 1:0 | ||||
| 23. Round | 21/02/2010 | Athletic Club | - | CD Tenerife | 4:1 | ||||
| 24. Round | 28/02/2010 | Sevilla FC | - | Athletic Club | 0:0 | |
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| 28. Round | 25/03/2010 | Atlético Madrid | - | Athletic Club | 2:0 | |
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| 29. Round | 29/03/2010 | Athletic Club | - | Racing Santander | 4:3 | ||||
| 30. Round | 03/04/2010 | FC Barcelona | - | Athletic Club | 4:1 | ||||
| 32. Round | 15/04/2010 | Valencia CF | - | Athletic Club | 2:0 | ||||
| 34. Round | 26/04/2010 | CA Osasuna | - | Athletic Club | 0:0 | ||||
| 35. Round | 02/05/2010 | Athletic Club | - | RCD Mallorca | 1:3 | ||||
| 36. Round | 05/05/2010 | Athletic Club | - | Málaga CF | 1:1 | |
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| 37. Round | 08/05/2010 | Real Madrid | - | Athletic Club | 5:1 | ||||
| 38. Round | 15/05/2010 | Athletic Club | - | Deportivo La Coruña | 2:0 |
Spain