| 1. Round | 08/08/2009 | Valenciennes FC | - | AS Nancy Lorraine | 1:3 | ||||
| 2. Round | 15/08/2009 | Olympique Lyonnais | - | Valenciennes FC | 1:0 | ||||
| 9. Round | 17/10/2009 | Valenciennes FC | - | Grenoble Foot 38 | 2:0 | ||||
| 10. Round | 24/10/2009 | AS Saint-Étienne | - | Valenciennes FC | 0:2 |  |
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| 12. Round | 01/11/2009 | Stade Rennais | - | Valenciennes FC | 0:3 | ||||
| 13. Round | 07/11/2009 | Valenciennes FC | - | Montpellier HSC | 1:1 | ||||
| 14. Round | 21/11/2009 | Girondins Bordeaux | - | Valenciennes FC | 0:1 | ||||
| 15. Round | 28/11/2009 | Lille OSC | - | Valenciennes FC | 4:0 | ||||
| 18. Round | 19/12/2009 | Valenciennes FC | - | RC Lens | 0:0 | ||||
| 19. Round | 23/12/2009 | FC Lorient | - | Valenciennes FC | 3:2 | |
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| 20. Round | 16/01/2010 | Valenciennes FC | - | Toulouse FC | 1:3 | ||||
| 21. Round | 20/01/2010 | US Boulogne | - | Valenciennes FC | 0:2 | ||||
| 22. Round | 31/01/2010 | Valenciennes FC | - | FC Sochaux | 1:1 | ||||
| 23. Round | 07/02/2010 | Olympique Marseille | - | Valenciennes FC | 5:1 | |
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| 29. Round | 21/03/2010 | Montpellier HSC | - | Valenciennes FC | 2:1 |
France