| 4. Round | 06/12/2013 | Real Valladolid | - | Rayo Vallecano | 0:0 | ||||
| 4. Round | 19/12/2013 | Rayo Vallecano | - | Real Valladolid | 3:1 |
| 4. Round | 06/12/2013 | Real Valladolid | - | Rayo Vallecano | 0:0 | ||||
| 4. Round | 19/12/2013 | Rayo Vallecano | - | Real Valladolid | 3:1 |
| Jaime Jiménez Merlo | |
| Born: | 10.12.1980 |
| Place of birth: |
Valdepeñas, 
Spain |
| Nationality: |
Spain
|
| Height: | 188 cm |
| Weight: | 80 kg |
| Position(s): | Goalkeeper |