| 1. Round | 23/01/2020 | Progreso | - | Barcelona | 0:2 | ||||
| 1. Round | 30/01/2020 | Barcelona | - | Progreso | 3:1 | ||||
| 2. Round | 07/02/2020 | Barcelona | - | Sporting Cristal | 4:0 | ||||
| 2. Round | 14/02/2020 | Sporting Cristal | - | Barcelona | 2:1 | ||||
| 3. Round | 20/02/2020 | Barcelona | - | Cerro Porteño | 1:0 | ||||
| 3. Round | 26/02/2020 | Cerro Porteño | - | Barcelona | 0:4 | ||||
| Group 1 | 18/09/2020 | Barcelona | - | Atlético Junior | 1:2 | ||||
| Group 1 | 22/09/2020 | Barcelona | - | Flamengo RJ | 1:2 | ||||
| Group 1 | 01/10/2020 | Atlético Junior | - | Barcelona | 0:2 |
Argentina
Ecuador