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| 1st(1st leg) | Universidad de Chile | - | Internacional | 0:0 (0:0) | ||
| 2nd (2nd leg) | Internacional | - | Universidad de Chile | 2:0 (1:0) | ||
| 1st(1st leg): 04/02/2020 21:00 | 2nd (2nd leg): 11/02/2020 22:15 | Winner: Internacional | ||||
| 1st(1st leg) | Independiente Medellín | - | Deportivo Táchira | 4:0 (3:0) | ||
| 2nd (2nd leg) | Deportivo Táchira | - | Independiente Medellín | 2:0 (1:0) | ||
| 1st(1st leg): 05/02/2020 00:30 | 2nd (2nd leg): 11/02/2020 22:15 | Winner: Independiente Medellín | ||||
| 1st(1st leg) | Macará | - | Deportes Tolima | 0:1 (0:0) | ||
| 2nd (2nd leg) | Deportes Tolima | - | Macará | 1:0 (1:0) | ||
| 1st(1st leg): 05/02/2020 00:30 | 2nd (2nd leg): 12/02/2020 00:30 | Winner: Deportes Tolima | ||||
| 1st(1st leg) | Universitario de Deportes | - | Cerro Porteño | 1:1 (0:0) | ||
| 2nd (2nd leg) | Cerro Porteño | - | Universitario de Deportes | 1:0 (0:0) | ||
| 1st(1st leg): 05/02/2020 22:15 | 2nd (2nd leg): 12/02/2020 22:15 | Winner: Cerro Porteño | ||||
| 1st(1st leg) | Cerro Largo | - | Palestino | 1:1 (1:0) | ||
| 2nd (2nd leg) | Palestino | - | Cerro Largo | 5:1 (2:0) | ||
| 1st(1st leg): 05/02/2020 22:15 | 2nd (2nd leg): 12/02/2020 22:15 | Winner: Palestino | ||||
| 1st(1st leg) | The Strongest | - | Atlético Tucumán | 2:0 (1:0) | ||
| 2nd (2nd leg) | Atlético Tucumán | - | The Strongest | 6:5 (1:0, 2:0) pso | ||
| 1st(1st leg): 06/02/2020 00:30 | 2nd (2nd leg): 13/02/2020 00:30 | Winner: Atlético Tucumán | ||||
| 1st(1st leg) | Guaraní | - | Corinthians SP | 1:0 (1:0) | ||
| 2nd (2nd leg) | Corinthians SP | - | Guaraní | 2:1 (2:0) | ||
| 1st(1st leg): 06/02/2020 00:30 | 2nd (2nd leg): 13/02/2020 00:30 | Winner: Guaraní | ||||
| 1st(1st leg) | Barcelona | - | Sporting Cristal | 4:0 (2:0) | ||
| 2nd (2nd leg) | Sporting Cristal | - | Barcelona | 2:1 (0:0) | ||
| 1st(1st leg): 07/02/2020 00:30 | 2nd (2nd leg): 14/02/2020 00:30 | Winner: Barcelona | ||||
