| 1. Round | 04/08/2007 | Valenciennes FC | - | Toulouse FC | 3:1 | ||||
| 2. Round | 11/08/2007 | AS Saint-Étienne | - | Valenciennes FC | 3:1 | ||||
| 3. Round | 15/08/2007 | Valenciennes FC | - | Olympique Marseille | 2:1 |  |
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| 4. Round | 19/08/2007 | RC Lens | - | Valenciennes FC | 0:0 | ||||
| 28. Round | 08/03/2008 | Valenciennes FC | - | Lille OSC | 0:0 | ||||
| 29. Round | 15/03/2008 | Paris Saint-Germain | - | Valenciennes FC | 1:1 | |
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| 30. Round | 22/03/2008 | Valenciennes FC | - | Girondins Bordeaux | 3:1 | ||||
| 31. Round | 30/03/2008 | Valenciennes FC | - | Olympique Lyonnais | 1:2 | ||||
| 32. Round | 05/04/2008 | SM Caen | - | Valenciennes FC | 1:0 | ||||
| 33. Round | 12/04/2008 | Valenciennes FC | - | RC Strasbourg | 2:0 | ||||
| 36. Round | 03/05/2008 | AJ Auxerre | - | Valenciennes FC | 2:0 | |
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| 37. Round | 10/05/2008 | Valenciennes FC | - | OGC Nice | 1:2 | ||||
| 38. Round | 17/05/2008 | Toulouse FC | - | Valenciennes FC | 2:1 |
Brazil