| 8. Round | 15/11/2020 | Espanyol Barcelona [Women] | - | Sevilla FC [Women] | 0:3 | ||||
| 6. Round | 18/11/2020 | Espanyol Barcelona [Women] | - | Athletic Club [Women] | 2:1 | ||||
| 9. Round | 22/11/2020 | EDF Logroño [Women] | - | Espanyol Barcelona [Women] | 1:1 | ||||
| 11. Round | 13/12/2020 | Espanyol Barcelona [Women] | - | Real Madrid [Women] | 1:8 | ||||
| 13. Round | 22/12/2020 | Espanyol Barcelona [Women] | - | Real Betis [Women] | 2:1 | ||||
| 18. Round | 31/01/2021 | Espanyol Barcelona [Women] | - | EDF Logroño [Women] | 1:0 | ||||
| 19. Round | 07/02/2021 | Athletic Club [Women] | - | Espanyol Barcelona [Women] | 3:0 | ||||
| 16. Round | 14/02/2021 | Rayo Vallecano [Women] | - | Espanyol Barcelona [Women] | 2:0 | ||||
| 21. Round | 07/03/2021 | Real Madrid [Women] | - | Espanyol Barcelona [Women] | 4:1 | ||||
| 22. Round | 13/03/2021 | Espanyol Barcelona [Women] | - | Santa Teresa CD [Women] | 1:2 | ||||
| 29. Round | 09/05/2021 | Espanyol Barcelona [Women] | - | Levante UD [Women] | 1:1 | ||||
| 31. Round | 22/05/2021 | Espanyol Barcelona [Women] | - | FC Barcelona [Women] | 2:3 |  |
Spain