| 5. Round | 15/08/2020 | Barcelona | - | Orense SC | 1:0 |  |
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| 6. Round | 18/08/2020 | Deportivo Cuenca | - | Barcelona | 0:3 | ||||
| 7. Round | 24/08/2020 | Barcelona | - | Emelec | 2:1 | ||||
| 8. Round | 27/08/2020 | Guayaquil City | - | Barcelona | 2:1 | |
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| 9. Round | 29/08/2020 | Barcelona | - | Olmedo | 3:1 | ||||
| 10. Round | 02/09/2020 | Barcelona | - | Aucas | 4:2 | |
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| 11. Round | 05/09/2020 | Mushuc Runa | - | Barcelona | 1:2 | ||||
| 13. Round | 10/09/2020 | Macará | - | Barcelona | 1:1 | ||||
| 14. Round | 27/09/2020 | Independiente del Valle | - | Barcelona | 1:1 |  |
Ecuador